Electrochemical Systems, 4th Edition
- Length: 608 pages
- Edition: 4
- Language: English
- Publisher: Wiley
- Publication Date: 2021-01-07
- ISBN-10: 1119514606
- ISBN-13: 9781119514602
- Sales Rank: #849511 (See Top 100 Books)
Provides a comprehensive understanding of a wide range of systems and topics in electrochemistry
This book offers complete coverage of electrochemical theories as they pertain to the understanding of electrochemical systems. It describes the foundations of thermodynamics, chemical kinetics, and transport phenomena―including the electrical potential and charged species. It also shows how to apply electrochemical principles to systems analysis and mathematical modeling. Using these tools, the reader will be able to model mathematically any system of interest and realize quantitative descriptions of the processes involved.
This brand new edition of Electrochemical Systems updates all chapters while adding content on lithium battery electrolyte characterization and polymer electrolytes. It also includes a new chapter on impedance spectroscopy. Presented in 4 sections, the book covers: Thermodynamics of Electrochemical Cells, Electrode Kinetics and Other Interfacial Phenomena, Transport Processes in Electrolytic Solutions, and Current Distribution and Mass Transfer in Electrochemical Systems. It also features three appendixes containing information on: Partial Molar Volumes, Vectors and Tensors, and Numerical Solution of Coupled, Ordinary Differential Equations.
- Details fundamental knowledge with a thorough methodology
- Thoroughly updated throughout with new material on topics including lithium battery electrolyte characterization, impedance analysis, and polymer electrolytes
- Includes a discussion of equilibration of a charged polymer material and an electrolytic solution (the Donnan equilibrium)
- A peerless classic on electrochemical engineering
Electrochemical Systems, Fourth Edition is an excellent resource for students, scientists, and researchers involved in electrochemical engineering.
Cover Series Title Page Title Page Copyright Preface to the Fourth Edition Preface to the Third Edition Preface to the Second Edition Preface to the First Edition Reference Chapter 1: Introduction 1.1 Definitions 1.2 Thermodynamics and Potential 1.3 Kinetics and Rates of Reaction 1.4 Transport 1.5 Concentration Overpotential and the Diffusion Potential 1.6 Overall Cell Potential Problems Notation Part A: Thermodynamics of Electrochemical Cells Chapter 2: Thermodynamics in Terms of Electrochemical Potentials 2.1 Phase Equilibrium 2.2 Chemical Potential and Electrochemical Potential 2.3 Definition of Some Thermodynamic Functions 2.4 Cell with Solution of Uniform Concentration 2.5 Transport Processes in Junction Regions 2.6 Cell with a Single Electrolyte of Varying Concentration 2.7 Cell with Two Electrolytes, One of Nearly Uniform Concentration 2.8 Cell with Two Electrolytes, Both of Varying Concentration 2.9 Lithium–Lithium Cell With Two Polymer Electrolytes 2.10 Standard Cell Potential and Activity Coefficients 2.11 Pressure Dependence of Activity Coefficients 2.12 Temperature Dependence of Cell Potentials Problems Notation References Chapter 3: The Electric Potential 3.1 The Electrostatic Potential 3.2 Intermolecular Forces 3.3 Outer and Inner Potentials 3.4 Potentials of Reference Electrodes 3.5 The Electric Potential in Thermodynamics Notation References Chapter 4: Activity Coefficients 4.1 Ionic Distributions in Dilute Solutions 4.2 Electrical Contribution to the Free Energy 4.3 Shortcomings of the Debye–Hückel Model 4.4 Binary Solutions 4.5 Multicomponent Solutions 4.6 Measurement of Activity Coefficients 4.7 Weak Electrolytes Problems Notation References Chapter 5: Reference Electrodes 5.1 Criteria for Reference Electrodes 5.2 Experimental Factors Affecting Selection of Reference Electrodes 5.3 The Hydrogen Electrode 5.4 The Calomel Electrode and Other Mercury–Mercurous Salt Electrodes 5.5 The Mercury–Mercuric Oxide Electrode 5.6 Silver–Silver Halide Electrodes 5.7 Potentials Relative to a Given Reference Electrode Notation References Chapter 6: Potentials of Cells with Junctions 6.1 Nernst Equation 6.2 Types of Liquid Junctions 6.3 Formulas for Liquid‐Junction Potentials 6.4 Determination of Concentration Profiles 6.5 Numerical Results 6.6 Cells with Liquid Junction 6.7 Error in the Nernst Equation 6.8 Potentials Across Membranes 6.9 Charged Membranes Immersed in an Electrolytic Solution Problems Notation References Part B: Electrode Kinetics and other Interfacial Phenomena Chapter 7: Structure of the Electric Double Layer 7.1 Qualitative Description of Double Layers 7.2 Gibbs Adsorption Isotherm 7.3 The Lippmann Equation 7.4 The Diffuse Part of the Double Layer 7.5 Capacity of the Double Layer in the Absence of Specific Adsorption 7.6 Specific Adsorption at an Electrode–Solution Interface Problems Notation References Chapter 8: Electrode Kinetics 8.1 Heterogeneous Electrode Reactions 8.2 Dependence of Current Density on Surface Overpotential 8.3 Models for Electrode Kinetics 8.4 Effect of Double‐Layer Structure 8.5 The Oxygen Electrode 8.6 Methods of Measurement 8.7 Simultaneous Reactions Problems Notation References Chapter 9: Electrokinetic Phenomena 9.1 Discontinuous Velocity at an Interface 9.2 Electro‐Osmosis and the Streaming Potential 9.3 Electrophoresis 9.4 Sedimentation Potential Problems Notation References Chapter 10: Electrocapillary Phenomena 10.1 Dynamics of Interfaces 10.2 Electrocapillary Motion of Mercury Drops 10.3 Sedimentation Potentials for Falling Mercury Drops Notation References Part C: Transport Processes in Electrolytic Solutions Chapter 11: Infinitely Dilute Solutions 11.1 Transport Laws 11.2 Conductivity, Diffusion Potentials, and Transference Numbers 11.3 Conservation of Charge 11.4 The Binary Electrolyte 11.5 Supporting Electrolyte 11.6 Multicomponent Diffusion by Elimination of the Electric Field 11.7 Mobilities and Diffusion Coefficients 11.8 Electroneutrality and Laplace'S Equation 11.9 Moderately Dilute Solutions Problems Notation References Chapter 12: Concentrated Solutions 12.1 Transport Laws 12.2 The Binary Electrolyte 12.3 Reference Velocities 12.4 The Potential 12.5 Connection with Dilute‐Solution Theory 12.6 Example Calculation Using Concentrated Solution Theory 12.7 Multicomponent Transport 12.8 Liquid‐Junction Potentials Problems Notation References Chapter 13: Thermal Effects 13.1 Thermal Diffusion 13.2 Heat Generation, Conservation, and Transfer 13.3 Heat Generation at an Interface 13.4 Thermogalvanic Cells 13.5 Concluding Statements Problems Notation References Chapter 14: Transport Properties 14.1 Infinitely Dilute Solutions 14.2 Solutions of a Single Salt 14.3 Mixtures of Polymers and Salts 14.4 Types of Transport Properties and Their Number 14.5 Integral Diffusion Coefficients for Mass Transfer Problem Notation References Chapter 15: Fluid Mechanics 15.1 Mass and Momentum Balances 15.2 Stress in a Newtonian Fluid 15.3 Boundary Conditions 15.4 Fluid Flow to a Rotating Disk 15.5 Magnitude of Electrical Forces 15.6 Turbulent Flow 15.7 Mass Transfer in Turbulent Flow 15.8 Dissipation Theorem for Turbulent Pipe Flow Problem Notation References Part D: Current Distribution and Mass Transfer in Electrochemical Systems Chapter 16: Fundamental Equations 16.1 Transport in Dilute Solutions 16.2 Electrode Kinetics Notation Chapter 17: Convective‐Transport Problems 17.1 Simplifications for Convective Transport 17.2 The Rotating Disk 17.3 The Graetz Problem 17.4 The Annulus 17.5 Two‐Dimensional Diffusion Layers in Laminar Forced Convection 17.6 Axisymmetric Diffusion Layers in Laminar Forced Convection 17.7 A Flat Plate in a Free Stream 17.8 Rotating Cylinders 17.9 Growing Mercury Drops 17.10 Free Convection 17.11 Combined Free and Forced Convection 17.12 Limitations of Surface Reactions 17.13 Binary and Concentrated Solutions Problems Notation References Chapter 18: Applications of Potential Theory 18.1 Simplifications For Potential‐Theory Problems 18.2 Primary Current Distribution 18.3 Secondary Current Distribution 18.4 Numerical Solution by Finite Differences 18.5 Principles of Cathodic Protection Problems Notation References Chapter 19: Effect of Migration on Limiting Currents 19.1 Analysis 19.2 Correction Factor for Limiting Currents 19.3 Concentration Variation of Supporting Electrolyte 19.4 Role of Bisulfate Ions 19.5 Paradoxes with Supporting Electrolyte 19.6 Limiting Currents for Free Convection Problems Notation References Chapter 20: Concentration Overpotential 20.1 Definition 20.2 Binary Electrolyte 20.3 Supporting Electrolyte 20.4 Calculated Values Problems Notation References Chapter 21: Currents Below the Limiting Current 21.1 The Bulk Medium 21.2 The Diffusion Layers 21.3 Boundary Conditions and Method of Solution 21.4 Results for the Rotating Disk Problems Notation References Chapter 22: Porous Electrodes 22.1 Macroscopic Description of Porous Electrodes 22.2 Nonuniform Reaction Rates 22.3 Mass Transfer 22.4 Battery Simulation 22.5 Double‐Layer Charging and Adsorption 22.6 Flow‐Through Electrochemical Reactors Problems Notation References Chapter 23: Semiconductor Electrodes 23.1 Nature of Semiconductors 23.2 Electric Capacitance at the Semiconductor–Solution Interface 23.3 Liquid‐Junction Solar Cell 23.4 Generalized Interfacial Kinetics 23.5 Additional Aspects Problems Notation References Chapter 24: Impedance 24.1 Frequency Dispersion at a Disk Electrode 24.2 Modulated Flow With a Disk Electrode 24.3 Porous Electrodes for Batteries 24.4 Kramers–Kronig Relation Problems Notation References Appendix A: Partial Molar Volumes Appendix B: Vectors and Tensors Reference Appendix C: Numerical Solution of Coupled, Ordinary Differential Equations C.1 Errors in Finite‐Difference Calculations C.2 Convergence Over Nonlinearities C.3 Solution of Coupled, Linear, Difference Equations C.4 Program for Coupled, Linear Difference Equations C.5 Program for the Effect of Ionic Migration on Limiting Currents C.6 Second Example: Multicomponent Diffusion C.7 Discussion and Conclusions References Index End User License Agreement
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